Sometimes when looking at the pace of results coming out of the 2D material community, I am reminded of an old joke from
Tom Lehrer about super-productive people: "It's people like that who make you realize how little you've accomplished. It's a sobering thought, for example, that, when Mozart was my age, he had been dead for two years." (See
here and then listen to the whole album -
National Brotherhood Week has particular resonance this year.).
Recently in the arxiv, there were two different back-to-back preprint pairs uploaded by extremely strong collaborations in the trade of creating new condensed matter systems at the interfaces of stacked
van der Waals materials (systems like graphene and mica, that can be exfoliated down to atomically thin layers).
The first pair of papers (and my apologies if I missed others) were
this one and
this one. In the former, the investigators take advantage of the energies of the bands in \(\alpha\)-RuCl
3, and find that when it is layered stacked with various 2D materials (graphene, bilayer graphene, WSe
2, electrons are spontaneously transferred from the 2D materials to the \(\alpha\)-RuCl
3 (The normally empty conduction band of \(\alpha\)-RuCl
3 lies at lower energy than the top of the valence band of the 2D material.) This leads to very high
hole concentrations within the graphene (etc.), with comparatively minimal disorder, reminiscent of
modulation doping, the technique used to achieve outstanding charge mobility in 2D electron and hole gases. The latter paper is complementary to the former: the investigators use near-field optical techniques to look at both the plasmon properties of the graphene in such structures, and can back out the optical conductivity of the now-electron-doped \(\alpha\)-RuCl
3.
The second pair of papers,
this one and
this one, show a whole hierarchy of insulating states that appear in moire bilayer structures made from twisted WS
2/WSe
2 bilayers. As I've written
before, putting together close but not identical lattices and/or twisting one layer relative to another leads to a
moire pattern, and therefore
superlattice for charge carriers at that interface. Both groups find (the first using optical methods, the second using microwave techniques) that for a large number of rational fraction ratios between the number of charge carriers and the number of lattice sites, the system is very strongly insulating. Each insulating state corresponds to a particular periodic arrangement of the charge carriers, trying to stay generally as far away from each other as possible to minimize their potential energy. These can be analogous to
Wigner crystals and
charge density waves.
Very cool stuff.