Dye-sensitized solar cells - an idea whose time has finally come?

Dyes are generally small molecules that have electronic transitions with energies corresponding to the visible spectrum of light (around 1-3 eV).  Around 35 years ago, the idea was put forward, particularly by Michael Grätzel and Brian O'Regan, to couple dye molecules to semiconductors and electrolytes, so that when the dye molecules are excited by light, the electrons/holes can be captured and used for photovoltaic power.  This is the concept behind dye-sensitized solar cells, as demonstrated early on here.  I wrote a little about this a long while ago. 

Energy diagram of a dye-sensitized photovoltaic
cell, from this paper. 

This is a compelling idea, and a main selling point is the hope that devices based on this could be cheap and much less energy-intensive in their manufacturing, since they could be made with materials that don't require high temperature synthesis or high purity, like Si solar cells.  After many years of effort, end-to-end power conversion efficiencies are up around 13% for outdoor solar illumination-type conditions.  Here (link to NIH free version) is a good review from 2021 that is very complete in summarizing progress.

So, 13% is nice, but it's hard to see that being competitive with Si for bulk photovoltaics, and perovskites, also solution-processable, are up over 25%, similar to Si.  Still, outdoor solar is not the only application!  This paper from 2017 showed that it is possible for dye-sensitized cells to get power conversion efficiencies up to around 30% for indoor lighting conditions (much lower intensity, different spectra than solar illumination).  That seems to be the basis for this story in today's Wall Street Journal, pointing out that there are actual consumer products coming to market that have dye-sensitized cells for indoor operations.  Very cool to see this product really start to make it out of the lab!  If one of my readers has a good, clear explanation of why the power conversion efficiency is so much better for indoor lighting conditions, please leave it in the comments.  

Items of interest

For the first post of the new calendar year, here are a few items that I thought were interesting:

• Here is a feature article in Science that talks about the experimental quest for detecting Majorana fermions in solid state systems, bookended by the story of Majorana's disappearance. 

• 

  Adapted from PRX 12, 045501 (2022)

  This brief column is a good starting point with references if you want to learn about altermagnetism.  For a lengthier, more technical discussion, see this PRX paper.  Quickly:  in local-moment ferromagnetism, the spins (and therefore magnetic moments) of electrons on lattice sites in a material spontaneously align (at least, in a single domain).  Shifting over one lattice site leads to the same pattern of magnetic moments, so the ferromagnetic ordered state is "invariant under a lattice translation".  In a local moment antiferromagnet, the spins alternate up and down on neighboring sites.  Shifting over one lattice site + a 180 degree rotation gets back the same pattern of magnetic moments, so the antiferromagnetic ordered state is invariant under a one lattice site translation plus 180 degree rotation.  It turns out, there is a third possibility:  in an "altermagnet", neighboring spins alternate up and down, but their local environments are rotated by 90 degrees, so that the ordered state is invariant under a spin flip plus a 90 degree rotation.  This has neat consequences for band structure and could lead to technological applications.
  
• A statement in the press this week caused me to realize that I've never written a nicely accessible post about magnetism and how it works.  Thinking about how to do that brought me back to this classic video with Richard Feynman, explaining why this can be very challenging.  It seems necessary to ask a general reader simply to accept certain postulates - for example, that electrons, which are nominally point particles, have angular momentum called "spin", and that associated with that spin is a magnetic moment, so that electrons act in some sense like little magnetic dipoles.  That really is remarkable, and in trying to find a way to think about this that is more accessible, I found this classic paper (pdf here) by Ohanian.  My conclusion:  I still need to think about this further, particularly the connection between the classical dipolar \(1/r^{3}\) field from a magnetic dipole and the fact that spin for an electron is a quantum mechanical quantity that follows its particular rules.
• N. David Mermin posted a neat little autobiographical essay on the arxiv yesterday.  Fun to read, especially if you are familiar with his writing.

Very brief end of the year round-up

It's hard to believe that it's already the end of 2023.  It's been a busy year for condensed matter; it's unfortunate that two of the biggest stories (problems with high pressure superconductivity papers; the brief excitement about LK99, the not-actually-a-superconductor) were probably the field's highest profile events.  Still, hopefully the latter at least had the effect of bringing to the public a little bit of the excitement and potential of how condensed matter and materials physics affects our lives.  Physics World summarizes some of their picks for big materials-related stories of 2023 here.  Similarly, here are Quanta's choices for biggest physics stories of the year, and these are the choices from the editors of APS's Physics.  

It's been a busy year personally, with lots going on and too much proposal writing, but at least my blog posting was more frequent than in 2022.  It's still surprising to me that I've been writing this since mid-2005, enough to see almost the entire lifecycle of blogging.  Happy New Year to my readers, and if there are any particular topics about which you think I should write, please let me know in the comments.  I'm always looking for CM/materials concepts that I can try to explain on a non-specialist accessible level.  Still looking for the time and appealing perspective to write that popular book....

Anyway, I hope you have a very happy new year, and best wishes for a great 2024.

New paper - plasmons, excitons, and steering energy

We have a new paper out in Nano Letters (arxiv version here), and I wanted to explain a bit about it and why I think it's a really cool result.   

I've written before about the Purcell Effect.  When we study quantum mechanics, we learn that the rates of processes, like the spontaneous emission of light from an atom, are actually malleable.  The rate of a particular process is usually proportional to the number of ways that process can happen - this is quantified in something called Fermi's Golden Rule.  When we are talking about something like emission of light from an atom, the rate is proportional to the number of possible final states of the photon.  We know how to count those states in a given energy range in free space, and Purcell pointed out that by placing that atom in an optical cavity, we alter the density of final states as a function of frequency, \(\rho(\omega)\) from its empty space value, and hence can change the rate of emission.  Pretty wild that placing a system in a cavity can alter the flow of energy in that system away from what it would otherwise be.

I've also written before about what happens we take two resonators and couple them together - we get "hybridization" or "new normal modes".  If you take a mass on a spring (natural frequency \(\omega_0 = \sqrt{k/m}\)) and couple it mechanically to another identical mass on an identical spring, the coupled system will now have two resonances, one above and one below \(\omega_{0}\).  The chemistry analog of this is, bonding two hydrogen atoms (each with 1s orbitals) together leads to two \(\sigma\) orbitals, one bonding and one antibonding.  

In the new paper, we start with a little metal tunnel junction that hosts plasmonic resonances, like the junctions I wrote about here.  We showed in that paper and subsequent work that it is possible to use an applied voltage and current to get some of the electrons, right near where the electrodes almost touch, to become effectively so hot that they glow (emitting light at energies larger than the applied voltage), while the atomic lattice itself remains cold.  The light emission process here is the radiative recombination of hot electrons and holes in the metal, where an electron drops down in energy to fill in a hole and spit out a photon.  The plasmon resonances of the bare metal act like a sort of cavity, shaping the density of photon states \(\rho(\omega)\), as we also showed here.  The plasmons, set by the metal shape and electronic properties, actually affect the rate at which the electrons and holes in that same metal radiatively combine.

Left: A thin flake of WSe2 is placed on a plasmonic
Au junction.  Right: Overbias light emission from the
device at a particular emitted polarization shows a big
peak splitting right around where the exciton resonance
is of the WSe2 (orange curve).  Adapted from the
SI of this paper.

The wrinkle in the new paper is that we couple that metal plasmonic junction with a thin (few nm) layer of 2D semiconductor by placing the semiconductor on top of the metal.  The semiconductor can host excitons, bound electron-hole pairs, and if the semiconductor is excited with enough energy to create them, the excitons can radiatively annihilate, leading to a comparatively narrow resonance at an energy that overlaps the plasmon resonances of the metal junction.  Thanks to hybridization between the plasmons in the metal and the excitons in the semiconductor, the photon density of states now has a split peak structure ("upper and lower plexciton polariton resonances" if you are an expert).  Light emission in this device is still due to recombination of electrons and holes in the metal, but now the recombination dynamics of those electrons "feels" the strong coupling between the excitons and plasmons.  (The polarization of the emitted light is rather complicated because of the polarization properties of the plasmon resonances).  

There are a lot of interesting possibilities on where to go from here, but it's always amazing to me to see how this physics comes together.  In this case, by changing the optical environment of a metal structure, we can alter the fate of energy stored in the electrons of that metal.  Really neat.

AI/ML and condensed matter + materials science

Materials define the way we live.  That may sound like an exaggeration that I like to spout because I'm a condensed matter physicist, but it's demonstrably true.  Remember, past historians have given us terms like "Stone Age", "Bronze Age", and "Iron Age", and the "Information Age" has also been called the "Silicon Age".  (And who could forget plastics.)

Perhaps it's not surprising, then, that some of the biggest, most wealthy companies in the world are turning their attention to materials and the possibility that AI approaches could lead to disruptive changes.  As I mentioned last week, there have been recent papers (back to back in Nature) by the Google Deep Mind group on this topic.  The idea is to use their particular flavor of AI/machine learning to identify potential new compounds/solids that should be thermodynamically stable and synthesizable, and make predictions about their structures and properties.  This is not a new idea, in that the Materials Genome Initiative (started in 2011) has been working in this direction, compiling large amounts of data about solid materials and their properties, and the Materials Project has been pushing on efficient computational methods with the modest goal of computing "the properties of all inorganic materials and provid[ing] the data and associated analysis algorithms for every materials researcher free of charge".

In addition to the Google work, Microsoft has released on the arxiv their effort, MatterGen, which uses a generative AI approach to try to predict new stable materials with desirable properties, such as a target symmetry or chemical composition or mechanical/electronic/magnetic response.  An example from their paper is to try to find new magnetic materials that have industrially useful properties but do not involve rare earths.  

There is a long way to go on any of these projects, but it's easy to see why the approach is enticing.  Imagine saying, I want a material that's as electrically conductive and mechanically strong and workable as aluminum, but transparent in the visible, and having software give you a credible approach likely to succeed (rather than having to rely on a time-traveling Mr. Scott).  

I'd be curious to know readers' opinions of what constitute the biggest obstacles on this path.  Is it the reliability of computational methods at predicting formation energies and structures?  Is it the lack of rapid yet robust experimental screening approaches?  Is it that the way generative AI and related tools work is just not well-suited to finding truly new systems beyond their training sets?

Intriguing papers - exquisite thermal measurements + automated materials discovery/synthesis

It's a busy time, but I wanted to point out a couple of papers from this past week.

First, I want to point to this preprint on the arxiv, where the Weizmann folks do an incredibly technically impressive thing.  I'd written recently about the thermal Hall effect, when a longitudinal heat current (and temperature gradient) in the presence of a magnetic field results in a transverse temperature gradient as well as the usual longitudinal one.  One of the most interesting ways this can happen is if there are edge modes, excitations that propagate around the perimeter of a 2D system and can carry heat (even if they are neutral and don't carry charge).  Unsurprisingly, to measure thermal transport requires putting thermometers at different places on the sample and carefully measuring temperature differences.  Well, these folks have done just exquisitely nice measurements of Johnson-Nyquist noise in particular contacts for thermometry, and they can see the incredibly tiny heat currents carried by rather exotic edge modes in some unusual fractional quantum Hall states.  It's just a technical tour de force.

Second, on a completely unrelated note, there are back to back papers in Nature this week from the Google deep mind folks - their own write-up is here.  The first paper uses their methods to predict a large number of what are expected to be new stable crystal structures.  The second paper talks about how they used an automated/robot-driven lab to try to synthesize a bunch of these in an automated way and characterize the resulting material.  This is certainly thought-provoking.  It is worth noting that detailed characterization (including confirming that you've made what you were trying to make) and optimized synthesis of new materials is very challenging and of concern here.  Update:  there is further discussion of the characterization here (on LinkedIn by the authors) as well, and more on Twitter here and here.

Third, this paper looks extremely interesting.  It’s long been a staple of condensed matter theory to try to capture complex materials with effective low energy models, like suggesting the Hubbard model as a treatment of the essential physics of the cuprate superconductors.  The authors here report that they’ve done a more orbital-based/ab initio version of this, solved these models numerically, and state that they can reproduce details of the phase diagram of four of the cuprates spanning a big range of superconducting transition temperatures.  Seems like this may bode well for gaining insights into these systems.

Noise in a strange metal - pushing techniques into new systems

Over the holiday weekend, we had a paper come out in which we report the results of measuring charge shot noise (see here also) in a strange metal.   Other write-ups of the work (here and especially this nice article in Quanta here) do a good job of explaining what we saw, but I wanted to highlight a couple of specific points that I think deserve emphasis.  

In thermal equilibrium at some temperature \(T\), there are current and voltage fluctuations in a conductor - this is called Johnson-Nyquist noise - and it is unavoidable.  Shot noise in electrical current results from the granularity of charge and, as shown in its original incarnation (pdf is in German), from the statistical variation in the arrival times of electrons.   Shot noise is an "excess" noise that appears in addition to this, only when a conductor is driven out of equilibrium by an applied voltage and carries a net current.

While the idea of shot noise is tunnel junctions and vacuum tubes had been worked out a long time ago (see the above 1918 paper by Schottky), it was in the 1990s when people really turned to the question of what one should see in noise measurements in small metal or semiconductor wires.  Why don't we see shot noise in macroscopic conductors like your house wiring?  Well, shot noise requires some deviation of the electrons from their thermal equilibrium response - otherwise you would just have Johnson-Nyquist noise.  The electrons in a metal or semiconductor are coupled to the vibrations of the atoms (phonons) - the clearest evidence for this is that the decrease in scattering of the electrons by the phonons explains why metals become more conductive as temperature is decreased.  In conductors large compared to the (temperature-dependent) electron-phonon scattering length, the electrons should basically be in good thermal equilibrium with the lattice at temperature \(T\), so all that should be detected is Johnson-Nyquist noise.  To see shot noise in a wire, you'd need the wire to be small compared to that e-ph length, typically on the order of a micron at low temperatures.  In the 1980s and 1990s, it was now possible to make structures on that scale.

Fig. 4 from the paper

The theory of what should be seen was worked out in a couple of different ways, initially assuming that it is safe to describe the conductor as a Fermi gas (ignoring electron-electron interactions).  One approach started from the conduction-as-wave-transmission picture of Landauer (see here and here for two examples).  A complementary approach (see here) calculated noise from the electronic distribution functions and got the same answer for non-interacting electrons, that the current noise should be 1/3 of the classic Schottky result.  That factor of 1/3 is called the Fano factor, \(F\).   If electron-electron interactions are "turned on", allowing the electrons to exchange energy amongst themselves but not lose energy to the lattice, the noise is actually a bit larger, \(F \rightarrow \sqrt{3}/4\).   It turns out that these values were verified in experiments in gold wires (see here and here, though one has to be careful in experimental design to see  \(F \rightarrow \sqrt{3}/4\)).  This confirmation is a great triumph of our understanding of physics at these mesoscopic scales.  (Interestingly, similar results are expected even with a non-degenerate electron gas - see here and here.)

We applied these same experimental approaches to nanowires we made from exquisite films of a strange metal, YbRh2Si2, and we found that the noise is much reduced from the usual result seen in Au wires (which we also confirmed).  We tested whether phonons could be responsible for the noise suppression, applying the same approach as had been done in the '90s (measurements on wires tens of microns long, where e-ph scattering should be important), and found (in addition to further confirming the e-ph energy loss results in Au from the '90s) that energy loss to phonons can't explain what we see in YbRhsSi2.  

Some further points of interest:

• Until recently there really has not been much attempt to push the theoretical analysis of these kinds of measurements beyond the 1990s/early 2000s results.  My colleague Qimiao Si and his group have looked at whether strong Fermi liquid corrections affect the expected noise, and the answer is "no".  Of course, there are all kinds of additional complications that one could imagine.
• This work was only possible because of the existence of high quality thin films of the material, and the ability to fabricate nanostructures from this stuff without introducing so much disorder or chemical change as to ruin the material.  My collaborator Silke Bühler-Paschen and her group have spent years learning how to grow this and related materials, and long-term support for materials growth is critically important.  My student, the lead author on the study, did great work figuring out the fabrication.  It's really not trivial.  
• I think it's worthwhile to consider pushing older techniques into new regimes and applying them to new materials systems.  The heyday of mesoscopics in the 1990s doesn't need to be viewed as a closed, somewhat completed subfield, but rather as a base from which to consider new ways to characterize the rich variety of materials and phases that we have to play with in condensed matter.  

Faculty positions at Rice - follow-up

I had mentioned about 6 weeks ago that my department at Rice is searching in the quantum/AMO space for experiment and theory.   Now I want to put the larger context of this out there - Rice has four quantum-related searches going on right now:

Quantum theory (PHYA): https://apply.interfolio.com/131379

Quantum experiment (PHYA): https://apply.interfolio.com/131378

Quantum engineering (ECE): https://apply.interfolio.com/133316

Quantum materials (MSNE): https://apply.interfolio.com/135086

Interested candidates, we hope you will apply!  It's an exciting time here, and our quantum initiative folks can help make sure applications end up in the right place.  

Postdoctoral opportunities at Rice

I will be sending some emails shortly, but I wanted to point out postdoctoral opportunities here at Rice University.

The Smalley-Curl Institute is having a competition for two two-year postdoctoral fellow slots.  Click on the link for the details.  The requirements for a candidate:

• Nomination by current SCI faculty member
• Ph.D. in a field related to an SCI focus areas
• Successful Ph.D. thesis defense before start of appointment
• Ph.D. completed no more than three years before the start of the appointment

I would be happy to work with an interested, competitive candidate on this, and the deadline for applying is December 31.  Research areas in my lab these days include:  nanostructure-based studies of correlated quantum materials, including noise-based measurements; studies of spin transport and thermally driven spin effects in insulating magnets, from basic science to applications in low-power electronics; plasmon-based nanophotonic light sources and plasmonic junctions for physical chemistry.  If you're a student finishing up and are interested, please contact me, and if you're a faculty member working with possible candidates, please feel free to point out this opportunity. 

Rice also has a university-wide endowed honorific postdoctoral program called the Rice Academy of Fellows.   Like all such things, it's very competitive, and it similarly has a deadline of January 3, 2024.  Again, applicants have to have a faculty mentor, so in case someone is interested in working with me on this, please contact me via email. 

Scientific publishing - where are we going?

I think it's safe to say that anyone involved in scientific publishing will tell you that it's a mess and the trends are worrisome.  This week, this news release/article came out about this preprint which shows a number of the issues.  In brief (not all of this is in the preprint; some is me editorializing):

Figure 1 from this preprint

• The number of scientific papers being published is growing at a rate that looks completely unsustainable.  In my opinion, it's problematic on multiple levels.  There aren't enough reviewers (though that doesn't bother all publishers) and the average paper gets smaller and smaller readership (raising the question of why bother to publish papers that no one reads).  Does it make sense that the number of papers is skyrocketing while the number of PhDs granted is falling?
• Some publishers (especially Frontiers, Hindawi, MDPI) have boosted this by drastically cranking up the number of papers that they publish, through launching specialized journals with "special issues" designed to have super-short review times (assuming that review is even truly part of the process).  Lest you think this is only the provenance of publishers previously accused of being predatory, this week alone I have received five different "special issue" announcements from AIP journals.
• Why do people do this?  To try to game the impact factor calculations.  I've aired my grievances before about why journal impact factor is a lousy metric.  
• Why do people want to inflate impact factors?  Because that's how journals keep score, and some countries put in place big-time incentives tied to impact factor.  A publisher worries that if its journal's impact factor falls below some threshold, then the government of China, for example, will no longer view that journal as important, and then thousands of authors will stop submitting....
• Open access is a complicating factor, with some publishers charging absolutely sky-high charges, while at the same time having very high profit margins.  In the US, at least, those charges can be much larger than what grants will support.
• Over all of this is the concern that massively inflating the amount of scientific literature lowers its quality and undermines the credibility of science in general.  

Coincidentally, this week we hosted Steinn Sigurðsson for a colloquium.  He is now the scientific director of the arxiv, the preprint archive that went from a quick and dirty preprint sharing site in 1991 to an enormously important part of the global scientific enterprise.  In his talk he hit on some wild numbers.  The arxiv is up to around 20,000 papers per month now (!) (in part because new disciplines like quantitative biology are using the arxiv).  Thankfully the arxiv has recently landed some good support.  Their annual operating budget is around $3.5M, and this is an enormous bargain by any measure.  The arxiv is partnering with volunteer developers who are adding some neat functionality.  Unsurprisingly, generative AI is a serious concern, even more so than for the publishing houses.  

It's a transformative time, for sure.  Maybe what we are seeing is analogous to the fluctuations that happen when approaching a 2nd order phase transition, and we are headed for a real change in the way publishing works.  It's hard to see how the current trends can continue unabated.

Strategic planning + departmental reviews

It's been a while since I've written a post about the ways of academia, so I thought it might be time, though it's not exactly glamorous or exciting.  There are certain cycles in research universities, and two interrelated ones are the cycle of departmental strategic planning and the cycle of external departmental reviews.

Strategic planning can be extremely important, as it allows departments to take stock of where things are, what opportunities exist for improvement (in terms of research, teaching, departmental operations), and how the department aspires to move forward.  Often this can involve a hiring plan, based on demographic trends in the department (e.g., how many faculty lines are expected to be available in the next, say, five to seven years?), rising field/school/university research priorities (e.g., there is likely to be enormous investment in AI/ML in the coming years).  Discussions for strategic planning can be frought, since even maintaining departmental faculty size means alloting new hires between different possible research areas in a zero sum.  Still, arriving at a departmental plan is often expected at one level up (that of a School or College, depending on the university's org chart labeling scheme), and having a plan that department members know and understand is helpful in transparency of how decisions get made that shape the future of the department.  It doesn't make sense to do reformulate these plans at too rapid a frequency, since the ability to implement the plan can be strongly perturbed by, e.g., economic events, global pandemics, or big changes in university leadership.

Very often, deans (or provosts) also value periodic reviews of departments by an external visiting committee.  The visiting committee is typically put together with input from the department (research areas that should be represented, suggestions of possible reviewers) and invited to come for a couple of days of interviews and departmental presentations.  These reviews are typically very broad, looking at research, teaching, departmental climate, staffing levels and organization, infrastructure and space needs, etc.  It's important to talk to all stakeholders (departmental leadership, TT and NTT faculty, staff, undergrad and grad students, postdocs, and of course the dean or equivalent who is the intended recipient of the report). The expected output of these visits is a report to the dean (or provost).  Such a report can be very helpful for the department to get feedback on their plans and operations, and to serve as a way of putting priorities forward to the dean/provost level.  Similarly, often deans find these things valuable as a way to make certain arguments up to higher levels.  It seems to be human nature that a statement made by a nominally objective external committee can get more traction than the same statement made by locals.  Like strategic plans, it only makes sense to do external reviews on a timescale sufficiently long that the department would have a chance to address issues raised from the previous visit before the next one.  For both of these things, every five years is on the edge of being too frequent, and every ten years would definitely be too long an interval.

Participating in external visits takes time, but I've found it to be a very valuable experience.  It's allowed me to meet and work with faculty from a variety of places, and it can be very helpful to see how other institutions do things (even at a level of learning about tools like software that can be useful for tracking degree progress, or organizations that work to facilitate career placement at the graduate level).  

Reading material - orders of magnitude and difficult times

Over the past couple of weeks (and more) I have found a number of things to read that I wanted to pass on.  First, if you'd like a break from the seemingly continual stream of bad news in the world and enjoy good "think like a physicist"/dimensional analysis/order of magnitude estimate/Fermi problem discussions, I suggest:

• This paper (jstor link here) by Weisskopf, which does a great job at explaining quite a bit about matter, like the heights of mountains, e.g.  I had previously recommended this back in 2018.  
• That led me to a collection of Weisskopf's series of articles in the American Journal of Physics from back in the day, all under the name "Search for Simplicity".  Here is a link to a pdf file from the Minot Lab at Oregon State, and they have a bunch of other content along those lines.  
• The famed Edward Purcell also wrote a bunch of content for AJP about similar estimates; a page with links to those is here from the AAPT.
• The amazingly versatile and articulate Anthony Zee has written a wonderful textbook in this vein, called Fly By Night Physics.  It's great - highly recommended.

On a much more sobering note, I was saddened to learn of the grave illness of Prof. Jan Zaanen, who has terminal cancer.  A colleague brought my attention to an essay (link here) that Prof. Zaanen has written in the hopes that it will be widely read, and I pass it along.  

More soon.

Scientific travel

Particularly in these post-pandemic, climate-change-addled, zoom-enabled times, I appreciate the argument that it's always worth asking, "Is this trip really necessary?"  We are in the age of remote work and zoom seminars that are attended by people from all over the world.  Is there sufficient benefit to in-person visits to justify travel for work?  I just got back from my first really lengthy science trip in a number of years, and it was definitely very valuable, with experiences and knowledge transfer that just could not have happened nearly as readily any other way.  

I was fortunate enough to be able to attend and speak at a (beginning of October) summer school at ISTA, which is a large and growing scientific institute in Klosterneuberg, outside of Vienna, and I was also able to visit my collaborator's lab at TU Wien as well as the Vienna MicroKelvin Laboratory.  I spend the following week visiting the Laboratoire de Physique des Solides in Orsay, hanging out with the quantum electronics group.  Many thanks to my hosts for helping to organize these trips and for making me feel so welcome.

In-person visits allow for longer, extensive, interactive conversations - standing at a whiteboard, or having coffee, or pointing at actual apparatus.  It's a completely different experience than talking to someone over zoom or over the phone.  I think I did a better job explaining our work, and I definitely think that I learned a lot more about diverse topics than if I'd only had brief virtual interactions.   As an experimentalist, it can be very valuable to learn details about how some measurements are actually done, even including which bits of equipment and instrumentation are preferred by others.  (LPS has a ton of Rohde and Schwarz equipment, which I've really not seen to that extent in the US.  I'd also never heard of mycryofirm and their closed cycle cryostats.)

As an added bonus, I got to visit the Musée Curie in Paris and see Marie Curie's lab.  Here is a photograph of a Geiger counter that they'd made c. 1930.  Hand-soldered, uninsulated wires.  The biggest tube is the actual Geiger-Müller tube which produces current pulses when ionizing radiation zips through it.  The other two tubes make an amplifier to crank up the current pulses enough to turn an electric motor that drives a mechanical counter on the far right outside the box.

Hopefully I will finish up some writing and be posting more soon.

The Nobels, physics and chemistry

As you undoubtedly know, the 2023 Nobel in physics has been awarded to Pierre Agostini, Ferenc Krausz, and Anne L'Huillier, for the development of techniques associated with attosecond-scale optical pulses.  Here is the more popular write-up about this (including a good handwave of how attosecond pulses can be made) from the Nobel Foundation, and here is the more technical version.  A number of people (including friends and relatives) have asked me in the last couple of days about this, including what discoveries have these techniques led to, and how is this work different than preceding Nobel prizes (like the 1999 chemistry prize for femtosecond chemistry, the 2005 prize in physics for frequency combs, and the half of the 2018 physics prize for femtosecond pulsed lasers).  This isn't really my area of expertise, but my impression from talking with people is that the attosecond work is thus far more of a technical achievement than a technique that has led to a series of groundbreaking scientific results or technologies.  

Scientifically, the attosecond regime is very fast compared to the dynamics of, e.g., solids.  That said, attosecond techniques have been used to characterize condensed matter systems, as described here. Crudely speaking, the relevant energy scale associated with 100 as is \(h/10^{-16} s \sim\) 40 eV, the kind of energy (in the deep ultraviolet range) associated with photoemission.  It makes sense that some of the results highlighted in the Nobel citation have to do with using these methods to measure time delays associated with photoemission - like seeing that 4f electrons take longer to photoemit than s and p electrons in other bands.  If readers can point to a great explanation that goes deeper than this, please leave it in the comments.

The 2023 chemistry prize has been awarded to Moungi Bawendi, Louis Brus, and Alexey Ekimov, for the discovery and development of semiconductor nanocrystals now popularly called quantum dots.  These systems are absolutely great platforms to demonstrate quantum confinement.  By taking a bulk semiconductor and carving it up into pieces so small that the electronic wavefunctions get squeezed by the boundaries - this generally increases the energy spacings between levels, including the energy associated with the gap between the valence band and the conduction band. That is, a semiconductor that might fluoresce in the red in the bulk can be chopped into pieces that fluoresce in the green or the blue (higher energies).  The story of these materials (their growth, how to make them uniform and stable without bad defects at their surfaces) is very cool.  Quantum dots are now widely used as luminescent materials in display devices, and they are also broadly employed as fluorophores for biological imaging and related applications.  (Louis Brus is a Rice alumnus - huzzah!  I've never met Dr. Ekimov, but in my experience, Brus and Bawendi are both very nice, down-to-earth people whose groups write clear, non-hype-ridden papers.)

Faculty positions at Rice, + annual Nobel speculation

Trying to spread the word:

The Department of Physics and Astronomy at Rice University in Houston, Texas invites applications for two tenure-track faculty positions, one experimental and one theoretical, in the area of quantum science using atomic, molecular, or optical methods. This encompasses quantum information processing, quantum sensing, quantum networks, quantum transduction, quantum many-body physics, and quantum simulation conducted on a variety of platforms. The ideal candidates will intellectually connect AMO physics to topics in condensed matter and quantum information theory. In both searches, we seek outstanding scientists whose research will complement and extend existing quantum activities within the Department and across the University. In addition to developing an independent and vigorous research program, the successful applicants will be expected to teach, on average, one undergraduate or graduate course each semester, and contribute to the service missions of the Department and University. The Department anticipates making the appointments at the assistant professor level. A Ph.D. in physics or related field is required by June 30, 2024.

Applications for these positions must be submitted electronically at apply.interfolio.com/131378 (experimental) and apply.interfolio.com/131379 (theoretical). Applicants will be required to submit the following: (1) cover letter; (2) curriculum vitae; (3) statement of research; (4) statement on teaching; (5) statement on diversity, mentoring, and outreach; (6) PDF copies of up to three publications; and (7) the names, affiliations, and email addresses of three professional references. Rice University, and the Department of Physics and Astronomy, are strongly committed to a culturally diverse intellectual community. In this spirit, we particularly welcome applications from all genders and members of historically underrepresented groups who exemplify diverse cultural experiences and who are especially qualified to mentor and advise all members of our diverse student population. We will begin reviewing applications by November 15, 2023. To receive full consideration, all application materials must be received by December 15, 2023. The expected appointment date is July 2024.

____

In addition, the Nobels will be announced this week.  For the nth year in a row, I will put forward my usual thought that it could be Aharonov and Berry for geometric phases in physics (though I know that Pancharatnam is intellectually in there and died in 1969).  Speculate away below in the comments.  I'm traveling, but I will try to follow the discussion.

A few quick highlights

 It's been a very busy time, hence my lower posting frequency.  It was rather intense trying to attend both the KITP conference and the morning sessions of the DOE experimental condensed matter PI meeting (pdf of agenda here).  A few quick highlights that I thought were interesting:

• Kagome metals of the form AV3Sb5 are very complicated.  In these materials, in the a-b plane the V atoms form a Kagome lattice (before that one reader corrects me, I know that this is not formally a lattice from the crystallographic point of view, just using the term colloquially).  Band structure calculations show that there are rather flat bands (for an explanation, see here) near the Fermi level, and there are Dirac cones, van Hove singularities, Fermi surface nesting, etc.  These materials have nontrivial electronic topology, and CsV3Sb5 and KV3Sb5 both have charge density wave transitions and low-temperature superconductivity.  Here is a nice study of the CDW in CsV3Sb5, and here is a study that shows that there is no spontaneous breaking of time-reversal symmetry below that transition.  This paper shows that there is funky nonlinear electronic transport (apply a current at frequency \(\omega\), measure a voltage at frequency \(2 \omega\)) in CsV3Sb5 that is switchable in sign with an out-of-plane magnetic field.  Weirdly, that is not seen in KV3Sb5 even though the basic noninteracting band structures of the two materials are almost identical, implying that it has something to do with electronic correlation effects.
• Related to that last paper, here is a review article about using focused ion beams for sample preparation and material engineering.  It's pretty amazing what can be done with these tools, including carving out micro/nanostructured devices from originally bulk crystals of interesting materials.  
• The temperature-dependent part of the electrical resistivity of Fermi liquids is expected to scale like \(T^{2}\) as \(T \rightarrow 0\).  One can make a very general argument (that ignores actual kinematic restrictions on scattering) based on the Pauli exclusion principle that the inelastic e-e scattering rate should go like \(T^{2}\) (number of electron quasiparticles excited goes like \(T\), number of empty states available to scatter into also goes like \(T\)).  However, actually keeping track of momentum conservation, it turns out that one usually needs Umklapp scattering processes to get this.  That isn't necessary all the time, however.  In very low density metals, the Fermi wavevector is far from the Brillouin zone boundary and so Umklapp should not be important, but it is still possible to get \(T^{2}\) resistivity (see here as well).  Similarly, in 3He, a true Fermi liquid, there is no lattice, so there is no such thing as Umklapp, but at the lowest temperatures the \(T^{2}\) thermal conduction is still seen (though some weird things happen at higher temperatures). 

There are more, but I have to work on writing some other things.  More soon....

Meetings this week

This week is the 2023 DOE experimental condensed matter physics PI meeting - in the past I’ve written up highlights of these here (2021), here (2019), here (2017), here (2015), and here (2013).  This year, I am going to have to present remotely, however, because I am giving a talk at this interesting conference at the Kavli Institute for Theoretical Physics.  I will try to give some takeaways of the KITP meeting, and if any of the ECMP attendees want to give their perspective on news from the DOE meeting, I’d be grateful for updates in the comments.

Things I learned at the Packard Foundation meeting

Early in my career, I was incredibly fortunate to be awarded a David and Lucille Packard Foundation fellowship, and this week I attended the meeting in honor of the 35th anniversary of the fellowship program.  Packard fellowships are amazing, with awardees spanning the sciences (including math) and engineering, providing resources for a sustained period (5 years) with enormous flexibility.  The meetings have been some of the most fun ones I've ever attended, with talks by incoming and outgoing fellows that are short (20 min) and specifically designed to be accessible by scientifically literate non-experts.  My highlights from the meeting ten years ago (the last one I attended) are here.  Highlights from meetings back when I was a fellow are here, here, here, here.

Here are some cool things that I learned at the meeting (some of which I'm sure I should've known), from a few of the talks + posters.  (Unfortunately I cannot stay for the last day, so apologies for missing some great presentations.)   I will further update this post later in the day and tomorrow.

• By the 2040s, with the oncoming LISA and Cosmic Explorer/Einstein Telescope instruments, it's possible that we will be able to detect every blackhole merger in the entire visible universe.
• It's very challenging to have models of galaxy evolution that handle how supernovae regulate mass outflow and star formation to end up with what we see statistically in the sky
• Machine learning can be really good at disentangling overlapping seismic events.
• In self-propelled/active matter, it's possible to start with particles that just have a hard-shell repulsion and still act like there is an effective attractive interaction that leads to clumping.
• There are about \(10^{14}\) bacteria in each person, with about 360\(\times\) the genetic material of the person.  Also, the gut has lots of neurons, five times as many as the spinal cord (!).  The gut microbiome can seemingly influence concentrations of neurotransmitters.
• Bees can deliberately damage leaves of plants to stress the flora and encourage earlier and more prolific flowering.
• For some bio-produced materials that are nominally dry, their elastic properties and the dependence of those properties on humidity is seemingly controlled almost entirely by the water they contain.  
• It is now possible to spatially resolve gene expression (via mRNA) at the single cell level across whole slices of, e.g., mouse brain tissue.  Mind-blowing links here and here.
• I knew that ordinary human red blood cells have no organelles, and therefore they can't really respond much to stimuli.  What I did not know is that maturing red blood cells (erythrocyte precurors) in bone marrow start with nuclei and can participate in immune response, and that red blood cells in fetuses (and then at trace level in pregnant mothers) circulate all the different progenitor cells, potentially playing an important role in immune response.
• 45% of all deaths in the US can be attributed in part to fibrosis (scarring) issues (including cardiac problems), but somehow the uterus can massively regenerate monthly without scarring.  Also, zero common lab animals menstruate, which is a major obstacle for research; transgenic mice can now be made so that there are good animal models for study. 
• Engineered cellulose materials can be useful for radiative cooling to the sky and can be adapted for many purposes, like water harvesting from the atmosphere with porous fabrics.

What is the thermal Hall effect?

One thing that physics and mechanical engineering students learn early on is that there are often analogies between charge flow and heat flow, and this is reflected in the mathematical models we use to describe charge and heat transport.  We use Ohm's law, \(\mathbf{j}=\tilde{\sigma}\cdot \mathbf{E}\), which defines an electrical conductivity tensor \(\tilde{\sigma}\) that relates charge current density \(\mathbf{j}\) to electric fields \(\mathbf{E}=-\nabla \phi\), where \(\phi(\mathbf{r})\) is the electric potential.  Similarly, we can use Fourier's law for thermal conduction, \(\mathbf{j}_{Q} = - \tilde{\kappa}\cdot \nabla T\), where \(\mathbf{j}_{Q}\) is a heat current density, \(T(\mathbf{r})\) is the temperature distribution, and \(\tilde{\kappa}\) is the thermal conductivity.  

We know from experience that the electrical conductivity really has to be a tensor, meaning that the current and the electric field don't have to point along each other.  The most famous example of this, the Hall effect, goes back a long way, discovered by Edwin Hall in 1879.  The phenomenon is easy to describe.  Put a conductor in a magnetic field (directed along \(z\)), and drive a (charge) current \(I_{x}\) along it (along \(x\)), as shown, typically by applying a voltage along the \(x\) direction, \(V_{xx}\).  Hall found that there is then a transverse voltage that develops, \(V_{xy}\) that is proportional to the current.  The physical picture for this is something that we teach to first-year undergrads:  The charge carriers in the conductor obey the Lorentz force law and curve in the presence of a magnetic field.  There can't be a net current in the \(y\) direction because of the edges of the sample, so a transverse (\(y\)-directed) electric field has to build up.  

There can also be a thermal Hall effect, when driving heat conduction in one direction (say \(x\)) leads to an additional temperature gradient in a transverse (\(y\)) direction.  The least interesting version of this (the Maggi–Righi–Leduc effect) is in fact a consequence of the regular Hall effect:  the same charge carriers in a conductor can carry thermal energy as well as charge, so thermal energy just gets dragged sideways.   

Surprisingly, insulators can also show a thermal Hall effect.  That's rather unintuitive, since whatever is carrying thermal energy in the insulator is not some charged object obeying the Lorentz force law.  Interestingly, there are several distinct mechanisms that can lead to thermal Hall response.  With phonons carrying the thermal energy, you can have magnetic field affecting the scattering of phonons, and you can also have intrinsic curving of phonon propagation due to Berry phase effects.  In magnetic insulators, thermal energy can also be carried by magnons, and there again you can have Berry phase effects giving you a magnon Hall effect.  There can also be a thermal Hall signal from topological magnon modes that run around the edges of the material.  In special magnetic insulators (Kitaev systems), there are thought to be special Majorana edge modes that can give quantized thermal Hall response, though non-quantized response argues that topological magnon modes are relevant in those systems.  The bottom line:  thermal Hall effects are real and it can be very challenging to distinguish between candidate mechanisms. 

(Note: Blogger now compresses the figures, so click on the image to see a higher res version.)

Some interesting recent papers - lots to ponder

As we bid apparent farewell to LK99, it's important to note that several other pretty exciting things have been happening in the condensed matter/nano world.  Here are a few papers that look intriguing (caveat emptor:  I have not had a chance to read these in any real depth, so my insights are limited.)

• Somehow I had never heard of Pines' Demon until this very recent paper came out, and the story is told briefly here.  The wikipedia link is actually very good, so I don't know that I can improve upon the description.  You can have coupled collective modes for electrons in two different bands in a material, where the electrons in one band are sloshing anti-phase with the electrons in the other band.  The resulting mode can be "massless" (in the sense that its energy is linearly proportional to its momentum, like a photon's), and because it doesn't involve net real-space charge displacement, to first approximation it doesn't couple to light.  The UIUC group used a really neat, very sensitive angle-resolved electron scattering method to spot this for the first time, in high quality films of Sr2RuO4.  (An arxiv version of the paper is here.) 
• Here is a theory paper in Science (arxiv version) that presents a general model of so-called strange metals (ancient post on this blog).  Strange metals appear in a large number of physical systems and are examples where the standard picture of metals, Fermi liquid theory, seems to fail.  I will hopefully write a bit more about this soon.  One of the key signatures of strange metals is a low temperature electrical resistivity that varies like \(\rho(T) = \rho_{0} + AT\), as opposed to the usual Fermi liquid result \(\rho(T) = \rho_{0} + AT^{2}\).  Explaining this and the role of interactions and disorder is a real challenge.  Here is a nice write-up by the Simons Foundation on this.
• Scanning tunneling microscopy is a great spectroscopic tool, and here is an example where it's been possible to map out information about the many-body electronic states in magic-angle twisted bilayer graphene (arxiv version).  Very pretty images, though I need to think carefully about how to understand what is seen here.
• One more very intriguing result is this paper, which reports the observation of the fractional quantum anomalous Hall effect (arxiv version).  As I'd mentioned here, the anomalous Hall effect (AHE, a spontaneous voltage appearing transverse to a charge current) in magnetic materials was discovered in 1881 and not understood until recently.  Because of cool topological physics, some materials show a quantized AHE.  In 2D electron systems, the fractional quantum Hall effect is deeply connected to many-body interaction effects.  Seeing fractional quantum Hall states spontaneously appear in the AHE is quite exciting, suggesting that rich many-body correlations can happen in these topological magnetic systems as well.  Note: I really need to read more about this - I don't know anything in depth here.
• On the more applied side, this article is an extremely comprehensive review of the state of the art for transistors, the critical building block of basically every modern computing technology.  Sorry - I don't have a link to a free version (unless this one is open access and I missed it).  Anyway, for anyone who wants to understand modern transistor technology, where it is going, and why, I strongly encourage you to read this.  If I was teaching my grad nano class, I'd definitely use this as a reference.
• Again on the applied side, here is a neat review of energy harvesting materials.  There is a lot of interest in finding ways to make use of energy that would otherwise go to waste (e.g. putting piezo generators in your clothing or footwear that could trickle charge your electronics while you walk around).  
• In the direction of levity, in all too short supply these days, xkcd was really on-point this week.  For condensed matter folks, beware the quasiparticle beam weapon.  For those who do anything with electronics, don't forget this handy reference guide.